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Details of transitions of CI observed during the PLA of graphite and CVD diamond:[1]
Carbon (CI):
Ground state: 1s2 2s2 2p2, 3Po Ionisation Potential: 11.269 eV
|
State' |
State" |
E' (eV) |
E" (eV) |
|
|
1Po;2p3d |
1P;3p |
9.76 |
8.54 |
1012.1 |
|
3S;3p |
3Po;3s |
8.77 |
7.49 |
965.6 |
|
3S;3p |
3Po;3s |
8.77 |
7.48 |
961.8 |
|
3S;3p |
3Po;3s |
8.77 |
7.48 |
960.1 |
|
1D;3p |
1Po;3s |
9.00 |
7.68 |
940.0 |
|
3P;3p |
3Po;3s |
8.85 |
7.49 |
911.2 |
|
3P;3p |
3Po;3s |
8.85 |
7.49 |
909.5 |
|
1S;3p |
1Po;3s |
9.17 |
7.68 |
833.4 |
|
3Po;5s/4d |
3D;3p |
10.38 |
8.64 |
711.8 |
|
1Po;4d |
1P;3p |
10.42 |
8.54 |
658.7 |
|
3Fo;5d/6s |
3D;3p |
10.71 |
8.65 |
601.7 |
|
3P;4p |
3Do;2p3 |
10.08 |
7.95 |
579.8 |
|
1Po;5d |
1P;3p |
10.72 |
8.54 |
567.4 |
|
1P;4p |
1Po;3s |
9.99 |
7.68 |
538.1 |
|
1D;4p |
1Po;3s |
10.14 |
7.68 |
505.2 |
|
G;4f |
3Do;2p3 |
10.42 |
7.95 |
502.3 |
|
1S;4p |
1Po;3s |
10.2 |
7.68 |
493.2 |
|
3P;4p |
3Po;3s |
10.08 |
7.49 |
477.0 |
|
3P;5p |
3Po;3s |
10.57 |
7.49 |
403.2 |
|
1D;6p |
1Po;3s |
7.68 |
10.81 |
396.9 |
|
1S;6p |
1Po;3s |
10.82 |
7.68 |
394.0 |
|
1Po;3s |
1S;2p2 |
7.68 |
2.68 |
247.6¨ |
|
3Po;3s |
1S;2p3 |
7.68 |
1.26 |
193.0¨ |
¨ Emission observed in 2nd order transmission through monochromator.
[1] A. R. Striganov and N. S. Sventitskii in Tables of Spectral Lines of Neutral and Ionised Atoms, IFI/PLENUM. New York, 1968
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