A4. Linelist for carbon cations

 

Details of transitions of CII observed during the PLA of graphite and CVD diamond.[1]

Carbon (CII):

Ground state: 1s2 2s2 2p1, 2Po1/2 Ionisation Potential 24.381 eV

State'

State"

E' (eV)

E" (eV)

Observed Wavelength (nm)

4P;3p

4Po;3d

24.65

23.12

807.7

4P;3p

4Po;3d

24.65

23.12

806.2

4P;3p

4Po;3d

24.65

23.11

804.7

2D;3d

2Po;3p

18.05

16.33

723.5

2D;3d

2Po;3p

18.05

16.33

723.5

4Fo;3d

4D;3p

24.28

22.54

711.8

4S;3p

4Po;3d

24.65

22.90

706.4

4S;3p

4Po;3d

24.66

22.90

704.6

4D;3p

4Po;3s

22.54

20.71

678.5

2Po;3p

2S;3s

16.33

14.45

658.2

2Go;6g

2Fo;4f

22.87

20.95

646.1

2Fo;6f

2D;4d

22.86

20.84

615.1

2Do;3d

2P;3p

24.60

22.57

610.0

2Po;4p

2D;3d

20.15

18.05

589.4

4Po;3s

4S;3p

22.90

20.71

566.2

4Po;3s

4S;3p

22.90

20.71

564.8

4D;4p

4Fo;3d

26.63

24.27

526.0

4P;3p

4Po;3s

23.12

20.71

514.6

2G;4f

2Fo;3d

27.48

24.79

462.0

2F;4f

2Do;3d

27.41

24.60

441.2

4D;4f

4Po;3d

27.49

24.65

437.4

4Po;4s

4P;3p

25.98

23.11

432.2

2Fo;4f

2D;3d

20.95

18.05

426.8

2/4F;4f

4Do;3d

27.41

24.37

407.7

2/4D;4f

4Do;3d

27.49

24.37

397.0

2S;4s

2Po;3p

19.49

16.33

392.2

2/4G;4f

4Fo;3d

27.47

24.27

387.3

2D;3p

2Po;4p

23.38

20.15

383.7

4Po;4s

4D;3p

25.98

22.53

359.1

2Po;5p

2D;3d

21.73

18.05

336.3

2P;3p

2Do;2p3

22.57

18.65

316.8

2Fo;5f

2D;3d

22.19

18.04

299.3

2Po;3p

2S;2p2

16.33

11.96

283.7

2D;4d

2Po;3p

20.84

16.33

274.7

4Fo;4d

4D;3p

27.22

22.54

264.0

2Do;2p3

2P;2p2

18.65

13.72

250.8

Emission observed in 2nd order transmission through monochromator.



[1] Tables of Spectral Lines of Neutral and Ionised Atoms, A. R. Striganov, N. S. Sventitskii, IFI/PLENUM. New York, 1968


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