The Electrochemistry Group

Publications

Recent Publications

2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 - 1997

  1. Moore, A.; Celorrio, V., Montes de Oca, M.G., Plana, D., Hongthani, W., Lazaro, M.J. & Fermín D.J., «Insulating Diamond particles as substrate for Pd electrocatalysts», Chem. Comm., 47 (2011) 7656-7658
  2. Montes de Oca, M.G.; Kumarakura, H., Cherns, D. & Fermín D.J., «Hydrogen Adsorption at Strained Pd Nanoshells», J. Phys. Chem. C, 115, 21, (2011), 10489-10496.
  3. Hongthani, W.; Fox N.A. & Fermín D.J, «Electrochemical Properties of Two Dimensional Assemblies of Insulating Diamond Particles», Langmuir, 27, 8, 5112-5118.
  4. Kissling, G.P.; Miles D.O. & Fermín D.J, «Electrochemical charge transfer mediated by metal nanoparticles and quantum dots», Phys. Chem. Chem. Phys. DOI: 10.1039/c1cp21996k

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2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 - 1997

  1. Kissling, G.P.; Bünzli, C. & Fermín, D.J., «Tuning Electrochemical Rectification via Quantum Dot Assemblies», J. Am. Chem. Soc., 132 (2010) 16855-16861.
  2. Editor: Cosgrove, T., «Colloid Science: Principles, Methods and Applications», Wiley (2010)
  3. Editors: Abruña, H.D.; Fermín, D.J. & Marken, F., «Special Issue Dedicated to Laurence M. Peter», J. Electroanal. Chem., 646 (2010) 1-142.
  4. Bradbury, B.R.; Kuster, L. & Fermín, D.J., «Electrochemical reactivity of HOPG electrodes modified by ultrathin films and two-dimensional arrays of metal nanoparticles», J. Electroanal. Chem., 646 (2010) 114–123.
  5. Montes de Oca, M.G. & Fermín, D.J., «Electrochemical deposition of Te adlayers onto 3D networks of gold nanoparticles», Electrochim. Acta, 55 (2010) 8986-8991.
  6. Hongthani, W. & Fermín, D.J., «Layer-by-Layer assembly and redox properties of undoped HPHT diamond particles», Diamond & Related Materials, 19 (2010) 680–684.

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2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 - 1997

  1. Kissling, G.P. & Fermín, D.J., «Electrochemical Hole Injection Into the Valence Band of Thiol Stabilised CdTe Quantum Dots», Phys. Chem. Chem. Phys., 11 (2009) 10080-10086.
  2. Schnippering, M.; Zahn, A.; Liu, S.-X.; Leumann, C.; Decurtins, S. & Fermín, D.J., «Synthesis and Electrochemical Properties of TTF Modified Oligodeoxynucleotides»,Chem. Commun., (2009) 5552-5554.

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2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 - 1997

  1. Bradbury, C.R.; Zhao, J. & Fermín, D.J., «Distance-Independent Charge-Transfer Resistance at Gold Electrodes Modified by Thiol Monolayers and Metal Nanoparticles», J. Phys. Chem. C, 112 (2008) 10153-10160.
  2. Li, F.; Ciani, I.; Bertoncello, P.; Unwin, P.R.; Zhao, J.; Bradbury, C.R. & Fermín, D.J., «Scanning Electrochemical Microscopy of Redox-Mediated Hydrogen Evolution Catalyzed by Two-Dimensional Assemblies of Palladium Nanoparticles», J. Phys. Chem. C, 112 (2008) 9686-9694.
  3. Zhao, J.; Wasem, M.; Bradbury, C.R. & Fermín, D.J., «Charge Transport Across Self-Assembled Nanoscale Metal-Insulator-Metal Heterostructures», J. Phys. Chem. C, 112 (2008) 7284.
  4. Zhao, J.; Bradbury, C.R. & Fermín, D.J., «Long-Range Electronic Communication Between Metal Nanoparticles and Electrode Surfaces Separated by Polyelectrolyte Multilayer», J. Phys. Chem. C, 112 (2008) 6832-6841.

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table of contents image PCCP 2007

2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 - 1997

  1. Aslan, E.;Campana, F.P.; Fermín, D.J.; Siegenthaler, H.; Frehill, F. & Vos, J.G., «Molecularly Flat Films of the Redox [Os(bpy)2(PVP)5Cl]Cl Complex Obtained by Spontaneous Adsorption at HOPG Electrodes» Journal of Electroanalytical Chemistry 599 (2007) 267.
  2. Schnippering, M.; Carrara, M.; Foelske, A.; Kötz, R. & Fermín, D.J., «Electronic Properties of Ag Nanoparticle Arrays. A Kelvin Probe and High Resolution XPS Study» Physical Chemistry Chemical Physics 9 (2007) 725.

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2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 - 1997

  1. Fermín, D.J., «Linear and Non-Linear Spectroscopy at the Electrified Liquid|Liquid Interface», in Alkire, R.C.; Kolb, D.M.; Lipkowski, J. & Ross, P.N. (Eds.): Advances in Electrochemical Science and Engineering Vol IX: Diffraction and Spectroscopic Methods in Electrochemistry, Wiley-VCH Verlarg GmbH & Co. KGaA, Weinheim, (2006) pp. 127-161.
  2. Nagatani, H.; Suzuki, S.; Fermín, D.J.; Girault, H.H. & Nakatani, K., «Interfacial Behavior of Sulforhodamine 101 at the Polarized Water|1,2-Dichloroethane Interface Studied By Spectroelectrochemical Techniques» Analytical and Bioanalytical Chemistry, 386 (2006) 633.
  3. Fermín, D.J., «Nanoscale Probing of Electrode Surfaces by Scanning Force Microscopy» Chimia 60 (2006) A789.

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Earlier Publications

2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 to 1997

  1. Fermín, D.J., «Photoelectrochemistry at Dye-Sensitised Molecular and Nanostructured junctions», in Canudas, N.; Fuentes, J.M.; & Cova, B. (Eds.): Libro de Memorias del 1 Simposio Escuela Biofotónica y Fotoelectroquímica, Universidad Simón Bolívar, Caracas, (2005) pp. 202
  2. Zhao, J.; Bradbury, C.R..; Huclova, S.; Potapova, I.; Carrara, M. & Fermín D.J. «Nanoparticle-Mediated Electron Transfer Across Ultrathin Self-Assembled Films» J. Phys. Chem. B 109 (2005) 22985.
  3. Fermín D.J., «Review of The Nano-Micro Interface, Fecht H.-J. & Werner M. (eds)» ChemPhysChem (2005) 2205.
  4. Su, B.; Fermín D.J.; Abid J.-P., Eugster, N. & Girault, H.H., «Adsorption and Photoreactivity of CdSe Nanoparticles at Liquid|Liquid Interfaces» J. Electroanal. Chem. 583 (2005) 241.
  5. Samec, Z.; Eugster, N.; Fermín D.J. & Girault, H.H., «A Generalised Model for Dynamic Photocurrent Responses at Dye-Sensitised Liquid|Liquid Interface» J. Electroanal. Chem. 577 (2005) 323.

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Cover ChemPhysChem 2004

2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 - 1997

  1. Bauer, C.; Abid, J.-P.; Fermín, D.J. & Girault, H.H., «Ultrafast chemical interface scattering as an additional decay channel for nascent nonthermal electrons in small metal nanoparticles» J. Chem. Phys. 120 (2004) 9302-9315.
  2. Carrara, M.; Kakkassery, J.J.; Abid, J.-P. & Fermín, D.J., «Modulation of the work function in layer-by-layer assembly of metal nanoparticles and poly-L-lysine on modified Au surfaces» ChemPhysChem. 5 (2004) 571–575.
  3. Su, B.; Abid, J.-P.; Fermín, D.J.; Girault, H.H.; Hoffmanová, H.; Krtil, P. & Samec, Z., «Reversible Induced Assembly of Au Nanoparticles at Liquid|Liquid Interfaces» J. Am. Chem. Soc. 126 (2004) 916.
  4. Kakkassery, J.J.; Abid, J.-P.; Carrara, M. & Fermín, D.J., «Electrochemical and Optical Properties of Two Dimensional Electrostatic Assembly of Au Nanocrystals» Faraday Discuss. 125 (2004) 157.
  5. Hoffmannová, H.; Fermín, D.J. & Krtil, P., «Growth and Electrochemical Activity of the Poly-L-Lysine|Poly-L-Glutamic Acid Thin Layer – An EQCM and Electrochemical Study» J. Electroanal. Chem. 562 (2004) 261.

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2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 to 1997

  1. Fermín, D.J.; Jensen, H. & Girault, H.H., «Charge Transfer Kinetics at Liquid|Liquid Interfaces» E. J. Calvo (Ed.): Encyclopedia of Electrochemistry. Volume 2: Interfacial Kinetics and Mass Transport, Wiley-VCH, Weinheim, 2003, chapter 4.2, pp 360-390.
  2. Lahtinen, R.; Jensen, H. & Fermín, D.J., «Catalysis and Photocatalysis at Polarised Molecular Interfaces. An Electrochemical Approach to Catalytic Processes Based on Two-Phase Systems, Self-Organised Microheterogeneous Structures and Unsupported Nanoparticles» in A.G. Volkov (ed.), Interfacial Catalysis, Marcel Dekker Inc., New York, 2003, chapter 22, pp 611-643.
  3. Fermín, D.J.; Jensen, H.; Moser, J.E. & Girault, H.H., «Organisation and Reactivity of Nanoparticles at Molecular Interfaces. Part II. Dye Sensitisation of TiO2 Nanoparticles Electrostatically Assembled at the Water|1,2-Dichloroethane Junction» ChemPhysChem 4 (2003) 85.
  4. Eugster, N.; Jensen, H.; Fermín, D.J. & Girault, H.H., «Photoinduced Electron Transfer at Liquid|Liquid Interfaces. Part VII. Correlation Between self-Organisation and Structure of Water-Soluble Photoactive Species» J. Electroanal. Chem. 560 (2003) 143.
  5. Eugster, N.; Fermín, D.J. & Girault, H.H., «Photoinduced Electron Transfer at Liquid|Liquid Interfaces: Dynamics of the Heterogeneous Photoreduction of Quinones by Self-Assembled Porphyrin Ion Pairs» J. Am. Chem. Soc. 125 (2003) 4862.
  6. Nagatani, H.; Samec, Z.; Brevet, P.-F.; Fermín, D.J. & Girault, H.H., «Adsorption and Aggregation of meso-Tetrakis(4-carboxyphenyl)pophyrinato Zinc (II) at the Polarised Water|1,2-Dichlorethane Interface» J. Phys. Chem. B 107 (2003) 786.

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2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 to 1997

  1. Jensen, H.; Fermín, D.J.; Moser, J.E. & Girault, H.H., «Organisation and Reactivity of Nanoparticles at Molecular Interfaces. Part I. Photoelectrochemical Responses Involving TiO2 Nanoparticles Assembled at the Water|1,2-Dichloroethane Junctions» J. Phys. Chem. B 106 (2002) 10908.
  2. Eugster, N.; Fermín, D.J. & Girault, H.H., «Photoinduced Electron Transfer at Liquid|Liquid Interfaces. Part VI. On the Thermodynamic Driving Force Dependence of the Phenomenological Electron Transfer Rate Constant.» J. Phys. Chem. B 106 (2002) 3428.
  3. Nagatani, H.; Piron, A.; Brevet, P.-F.; Fermín, D.J. & Girault, H.H., «Surface Second Harmonic Generation of Cationic Water-Soluble Porphyrins at the Polarised Water|1,2-Dichloroethane Interface» Langmuir 18 (2002) 6647.
  4. Nakatani, K.; Nagatani, H.; Fermín, D.J. & Girault, H.H., «Transfer and Adsorption of 1-Pyrene Sulfonate at the Water|1,2-Dichloroethane Interface Studied By Potential Modulated Fluorescence Spectroscopy» J. Electroanal. Chem. 518 (2002) 1.
  5. Kakkassery, J.J.; Fermín, D.J. & Girault, H.H., «Photocurrent Responses at Dye Sensitised Ultrathin Polyelectrolyte Multilayers Supported on Gold Electrodes» Chem. Comm. 4 (2002) 1240.

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2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 to 1997

  1. Fermín, D.J. & Lahtinen, R., «Dynamic Aspects of Heterogeneous Electron Transfer at Liquid|Liquid Interfaces» in A.G. Volkov (ed.), Liquid interfaces in chemical, biological and pharmaceutical applications, Marcel Dekker Inc., New York, 2001, chapter 8, pp 179-227.
  2. Jensen, H.; Fermín, D.J. & Girault, H.H., «Photoinduced Electron Transfer at Liquid|Liquid Interfaces. Part V. Organisation of Water-Soluble Chlorophyll at the Water|1,2-Dichloroethane Interface» Phys. Chem. Chem. Phys. 3 (2001) 2503.
  3. Nagatani, H.; Fermín, D.J. & Girault, H.H., «A Kinetic Model for Adsorption and Transfer of Ionic Species at Polarised Liquid|Liquid Interfaces as Studied by Potential Modulated Fluorescence Spectroscopy» J. Phys. Chem. B 105 (2001) 9463.
  4. Osakai, T.; Jensen, H.; Nagatani, H.; Fermín, D.J. & Girault, H.H., »Mechanistic Aspects Associated with the Oxidation of L-Ascorbic Acid at the 1,2-Dichloroethane|Water Interface» J. Electroanal. Chem. 510 (2001) 43.
  5. Ulmeanu, S.; Lee, H.J.; Fermín, D.J.; Girault, H.H. & Shao, Y., «Voltammetry at a Liquid|Liquid Interface Supported on a Metallic Electrode» Electrochem. Comm. 3 (2001) 219.

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2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 to 1997

  1. Reymond, F.; Fermín, D.J.; Lee H.J. & Girault, H.H., «Electrochemistry at Liquid|Liquid Interfaces: Potential Applications» Electrochim. Acta, 45 (2000) 2647-2662.
  2. Jensen, H.; Kakkassery, J.J.; Nagatani, H.; Fermín, D.J. & Girault, H.H., «Photoinduced Electron Transfer at Liquid|Liquid Interfaces. Part IV. Orientation and Reactivity of Zinc tetra(4-carboxyphenyl) Porphyrin Self-Assembled at the Water|1,2-Dichloroethane Junction» J. Am. Chem. Soc. 122 (2000) 10943.
  3. Lahtinen, R., Fermín, D.J., Kontturi, K. & Girault, H.H., «Artificial Photosynthesis at Liquid|Liquid Interfaces. Photoreduction of Benzoquinone by Water-Soluble Porphyrin Species» J. Electroanal. Chem. 483 (2000) 81.
  4. Lahtinen, R.; Fermín, D.J.; Jensen, H.; Kontturi, K. & Girault, H.H., «Two-Phase Photocatalysis Mediated by Electrochemically Generated Pd-Nanoparticles» Electrochem. Comm. 2 (2000) 230.
  5. Nagatani, H.; Iglesias, R.A.; Fermín, D.J., Brevet, P.-F. & Girault, H.H., «Adsorption Behaviour of Charged Zinc Porphyrins at the Water|1,2-Dichloroethane Interface Studied by Potential Modulated Fluorescence Spectroscopy» J. Phys. Chem. B 104 (2000) 6869.

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2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 to 1997

  1. Fermín, D.J.; Ding, Z.; Duong, H.D.; Brevet, P.-F. & Girault, H.H., «Photoinduced Electron Transfer at Liquid|Liquid Interfaces. Part III. Photoelectrochemical Responses Involving Porphyrin Ion Pairs» J. Am. Chem. Soc. 121 (1999) 10203.
  2. Fermín, D.J.; Ding, Z.; Duong, H.D.; Brevet, P.-F. & Girault, H.H., «Photoinduced Electron Transfer at Liquid|Liquid Interfaces. Part II. A Study of the Electron Transfer and Recombination Dynamics by Intensity Modulated Photocurrent Spectroscopy» Phys. Chem. Chem. Phys. 1 (1999) 1461.
  3. Fermín, D.J.; Duong, H.D.; Ding, Z.; Brevet, P.-F. & Girault, H.H., «Solar Energy Conversion Using Dye Sensitised Liquid|Liquid Interfaces» Electrochem. Comm. 1 (1999) 29.
  4. Lee, H.J.; Fermín, D.J.; Corn, R.M. & Girault, H.H., «Marangoni Flow in Micro-channels» Electrochem. Comm. 1 (1999) 190.
  5. Fermín, D.J.; Ponomarev, E.A.; & Peter, L.M., «A Kinetic Study of CdS Photocorrosion by Intensity Modulated Photocurrent and Photoelectrochemical Impedance Spectroscopy» J. Electroanal. Chem. 473 (1999) 192.

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2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 to 1997

  1. Fermín, D.J.; Ding, Z.; Duong, H.D.; Brevet, P.-F. & Girault, H.H. «Photoinduced Electron Transfer at Liquid|Liquid Interfaces. Part I. Photocurrent Measurements Associated with Heterogeneous Quenching of Zinc Porphyrins.», J. Phys.Chem. B 102 (1998) 10334.
  2. Fermín, D.J.; Ding, Z.; Duong, H.D.; Brevet, P.-F. & Girault, H.H., «Photocurrent Responses Associated with Heterogeneous Electron Transfer at Liquid|Liquid Interfaces» Chem. Comm. 1 (1998) 1125.
  3. Ding, Z.; Fermín, D.J.; Brevet, P.-F. & Girault, H.H., «Spectroelectrochemical Approaches to Heterogeneous Electron Transfer at the Polarised Water|1,2-Dichloroethane Interface» J. Electroanal. Chem. 458 (1998) 139.
  4. Tomaszewski, L.; Ding, Z.; Fermín, D.J.; Caçote, H.M.; Pereira, C.M.; Silva, F. & Girault, H.H., «Spectroelectrochemical Study of the Copper(II) Transfer Assisted by 6,7-Dimethyl-2,3-Di(2-Pyridyl)Quinoxaline at the Water|1,2-Dichloroethane Interface» J. Electroanal. Chem. 453 (1998) 171.
  5. Ding, Z.; Reymond, F.; Baumgartner, P.; Fermín, D.J.; Brevet, P.-F.; Carrupt, P.A. & Girault, H.H., «Mechanism and Dynamics of Methyl and Ethyl Orange Transfer Across the Water|1,2 Dichloroethane Interface» Electrochim. Acta 44 (1998) 3.
  6. Fermín, D.J.; Ding, Z.; Brevet, P.-F. & Girault, H.H., «Potential Modulated Reflectance Spectroscopy of the Methyl Orange Transfer Across the Water|1,2-Dichloroethane Interface» J. Electroanal. Chem. 447 (1998) 125.

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2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2001 | 2000 | 1999 | 1998 | 1991 - 1997

  1. Fermín, D.J.; Ponomarev, E.A. & Peter, L.M., «Dynamics of Photo-Processes at the n-TiO2|Aqueous Electrolyte Interface» in K. Rajeshwar et al. (eds.), Proceedings of the symposium on photoelectrochemistry, vol. 97-20, The Electrochemical Society Inc. (1997) 62-71.
  2. Peter, L.M.; Ponomarev, E.A. & Fermín, D.J., «Intensity Modulated Photocurrent Spectroscopy: Reconciliation of the Phenomenological Approach with Multistep Electron Transfer Mechanism» J. Electroanal. Chem. 427 (1997) 79.
  3. Fermín, D.J.; Teruel, H. & Scharifker, B.R., «Changes In Population of Neutral Species and Charge Carriers During Electrochemical Oxidation of Polypyrrole» J. Electroanal. Chem. 401 (1996) 207.
  4. Scharifker, B.R. & Fermín, D.J., «The Role of Intermediates in Solution in the Initial Stages of Electrodeposition of Polypyrrole» J. Electroanal. Chem. 365 (1994) 35.
  5. Fermín, D.J. & Scharifker, B.R., «The Birth and Growth of Polypyrrole Films», Rev. Iberoamericana de Polímeros, 2 (1993) 17.
  6. Fermín, D.J. & Scharifker, B.R., «Products in Solution During Electrodeposition of Polypyrrole», J. Electroanal. Chem., 357 (1993) 273.
  7. Fermín, D.J., Mostany, J. & Scharifker, B.R., «Electronically Conducting Polymers: Synthesis and Electrochemical Properties of Polypyrrole» in S.G. Pandalai (ed.), Current topics in Electrochemistry, vol. 2, Council of Scientific Information, India (1993) 131-144.
  8. Fermín, D.J. & Scharifker, B.R., «Formation and Growth of Polypyrrole Films», Memorias del 3 Simposio Latianoamericano de Polímero, Sociedad Venezolana de Polímeros, (1993) pp. 95-100.
  9. Fermín, D.J. & Scharifker, B.R., «Spectroscopic Identification of Intermediates During Pyrrole Oxidation», in O. Perez de Marquez et al. (eds.), Libro de Memorias del 5th Encuentro Nacional de Electroquímica, Sociedad Venezolana de Electroquímica, (1992) pp. 279-290.
  10. Fermín, D.J. & Scharifker, B.R., «Polypyrrole Formation, Nucleation or Oligomer Precipitation», in O. Perez de Marquez et al. (eds.), Libro de Memorias del 5th Encuentro Nacional de Electroquímica, Sociedad Venezolana de Electroquímica, (1992) pp. 195-209.
  11. Fermín, D.J. & Scharifker, B.R., «Study of Intermediates in the Oxidation of Pyrrole in Aqueous Solution», in B.R. Scharifker et al. (eds.), Libro de Memorias del 4th Encuentro Nacional de Electroquímica, Sociedad Venezolana de Electroquímica, (1991) pp. 235-49.

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