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Chemistry of Kevlar 

 

 

 


Exceptional Strength

 

Kevlar is an exceptionally strong material, it is currently produced in three grades and even the weakest is much stronger than steel and also only half as dense. It is used for many applications where strength and low weight is paramount, such a bulletproof vests. The following table shows the strengths of all three types.

 

Grade

Density
g/cm^3

Tensile
Modulus
GPa

Tensile
Strength
GPa

Tensile
Elongation
%

29

1.44

83

3.6

4.0

49

1.44

131

3.6--4.1

2.8

149

1.47

186

3.4

2.0

 

Reasons For strength

 

The strength of Kevlar comes from its unusually regular internal structure; this has implications for the Hydrogen bonding which occurs between the electron dense oxygen atom and the electron deficient hydrogen. The all trans configuration, giving long straight chains, means that the hydrogen bonding can occur very regularly to form a very strong lattice, similar to those formed in crystals.

The fibres consequently have very few flaws and so are very difficult to break up.

         

 

 

 

 

 

 

This diagram shows an x-ray microscopy of the cut end of a Kevlar fibre, as can be seen it has a very symmetrical orientation.

 
 

 

         

 

 

 

 

 

 

 

 

 

 

 

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