Sonocatalyst
Ultrasound has potentially
important applications in both homogeneous and heterogeneous catalytic
systems. Heterogeneous catalysis is generally more industrially important
than homogeneous systems. For example, virtually all of the petroleum
industry is based on a series of catalytic transformations. Heterogeneous
catalysts often require rare and expensive metals. The catalytic converters
used on automobiles to lessen pollution, for example, use platinum or
rhodium, which are enormously expensive; rhodium costs about $1500 dollars
per ounce!
Using ultrasound offers some hope
of activating less reactive, but also less costly, metals. Some early
investigations of the effects of ultrasound on heterogeneous catalysis can
be found in the Soviet literature. In this early work, increases in turnover
rates were usually observed upon ultrasonic irradiation, but were rarely
more than 10-fold. In the case of modest rate increases, it appears likely
that the cause is increased effective surface area; this is especially
important in the case of catalysts supported on brittle solids.