The p molecular orbitals of 1,3-butadiene

 

What do the orbitals look like?

 

y1 -- lowest energy p M.O.

       -- no nodes other than in molecular plane: 

 

 

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y2 -- second lowest energy p MO 

       -- one node other than in molecular plane: 

 

 

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y3 -- first unoccupied antibonding p MO

       -- two nodes other than in molecular plane:

 

 

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y4 -- highest antibonding p MO 

       -- 3 nodes other than in molecular plane:

 

 

General conclusions about MOs