p electron bond order

 

·      We can also define a quantity which measures the strength of a p-electron bond between two atoms. 

·      This quantity depends on the electron density which is shared between two atoms:

 

p electron bond order for a-b bond (pab):

 

 

again ni is the number of electrons in molecular orbital i. 

 

If all the occupied molecular orbitals have two electrons in them then all the ni = 2 and:

 

 

 

Examples of atomic charge and bond order calculations