When we have established the molecular orbital energies E1 and E2, we can go back to the secular equations and insert, in turn, each of the energies. 

 

·    The equations now have non-trivial solutions.

·    Solving the equations gives us THE RATIO ci1/ci2.

 

We must still normalize the MOs, using the normalization condition:

 

 

From this,

 

 

Ş 

 

Since we know the ratio of the coefficients , this extra condition of normalization fixes the values of the coefficients absolutely.

 

The Hückel approximations