Estimating the value of b from correlations with experimental data
Benzene exhibits many unusual properties, for example it is more stable than expected, e.g. comparing enthalpies of hydrogenation with that expected for three double bonds.
the enthalpy of hydrogenation is DH = –119.7 kJ/mol
the enthalpy of hydrogenation is DH = –231.8 kJ/mol. This is slightly less than twice the value for cyclohexene, so 1,3-cyclohexadiene is slightly more stable than expected (by 7.6 kJ/mol).
the enthalpy of hydrogenation (DH = –208.4 kJ/mol) is much less negative than expected for 3 double bonds (3´–119.7kJ/mol = –359.1kJ/mol).
It is more stable than expected by (359.1 –208.4) = 150.7 kJ/mol (36 kcal/mol).
This extra stabilization energy is described as the (experimental) ‘resonance energy’ of benzene.
· Hückel Theory gives the delocalization energy of benzene as 2b, therefore we can estimate the value of b as –75.35 kJ/mol.
(Notice this is much lower than the value of b mentioned earlier – the reasons for this are discussed later).