SCHOOL OF CHEMISTRY

CHEMISTRY 1S

Calculus I - Dr Paul May

Problems 3

These are to be discussed in your tutorial in week 7.

1. Write down the derivatives of:

(a) 2ex (b) x2 - ex (c) e-5x (d) 5ln x (e) ln x2 (f) ln (1/x)

2. Find the gradient of each of the following curves at the specified value of x :

(a) y = ex - 2x where x = 0

(b) y = x2 + 2ex where x = 2

(c) y = ex(x3 - 2) where x = 1

3. Differentiate each of the following functions with respect to x :

(a) (3x + 1)2 (b) (2x4 - 5)½ (c) x(2x + 3)3

(d) (e) (f)

(g) ln (x + 1)2 (h) 5exp(x2 + 1) (i)

4. The Maxwell-Boltzmann distribution law for the speeds of molecules in a gas at temperature T states that:

where A is a proportionality constant and B is given by:

B = m/2kT.

Calculate the most probable velocity for an N2 molecule at a temperature of 300 K given the parameters: m = 4.65x10-26 kg, k = 1.38x10-23 J / deg.

[Hint: You will need to use the rule for a product of functions and the chain rule to find the value of for which N(ν) is a maximum.]


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