Sonochemistry is the emerging study of chemical reactions powered by high-frequency sound waves.
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Imagine you are riding a roller coaster. When you get to the top and the car free-falls speeding up until it reaches the bottom of the drop. And at the bottom, you would be crushed into your seat with a force equal to 1,000 billion times your weight. Obviously, more than your stomach would react to such a ride. As for the bubble, of air trapped in water, it responds to the extraordinary force by creating a flash of light only a tiny fraction of a second long. The light is mostly ultraviolet. Ultrasound wave can make the bubble repeat this wild free fall more than 30,000 times a second
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Ultrasonic
waves in liquid cause the formation of tiny bubbles that collapse so
quickly, and why such enormous temperatures and pressures, that novel
chemical reactions are generated. Chemical effects of ultrasound enhance reaction rates because of the formation of highly reactive radical species formed during cavitation in forms of bubbles. |
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Why bubble
gets hot?
When ultrasound is supplied in the system, bubbles react with the compression/expansion cycle of ultrasound causing it to expand and collapse in compression , hence energy is released in term of light and heat at the point of implosion. The high temperatures and pressures created during cavitation can even cause the bubbles to produce a flash of light (see sonoluminescence) and release enough energy to activate the reaction. (see Ultrasound page for more information about implosion) |
Fig3 - growth.collapse cycle of cavitation bubbles. |
pictures from :
http://pluto.apl.washington.edu/harlett2/artgwww/acoustic/medical/litho.html