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Colourings

The conjugated chain in carotenoids means that they absorb in the visible region and hence are coloured.  The absorption  spectrum below shows that beta-carotene absorbs most strongly between 400-500  nm.  This is the green/blue part of the spectrum.  So beta-carotene  appears orange, because the red/yellow colours are reflected back to us.

  absorption spectrum of beta-carotene
After Vetter et al. in Carotenoids (ed. O. Isler), Birkhauser Verlag, 1971 , p194

Natural colours

Carotenoids are one of the most important groups of natural pigments.  They are responsible for many of the yellow and orange colours of fruit and vegetables.   Beta-carotene is most abundant in carrots, of course, but is also found in pumpkins, apricots and nectarines.  Dark green vegetables such as spinach and broccoli are another good source.  In these the orange colour is masked by the green colour of chlorophyll.  This can be seen in leaves; in autumn, when the leaves die, the chlorophyll breaks down, and the yellow/red colours of the more stable carotenoids can be seen.

autumn leaves

See here for more information on natural sources of beta-carotene.

Artificial colours

margarine Natural extracts containing carotenoids, for example carrot extracts and red palm oil, have been used to colour foods for centuries.  Synthetic beta-carotene was first marketed as a food colouring by Roche in 1954.  It is mainly used for colouring margarine and butter; its vitamin A activity is an added benefit.  Other applications include ice-cream, fruit juice and the coatings of tablets.  Beta-carotene has an advantage over other artificial colours, for example azo dyes, because it occurs naturally in food and is so known to be safe.




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Page created by Martha Evens, School of Chemistry, University of Bristol