Interest in other cobalt metalloenzymes is growing.
The dehydration step in the
enzyme-coenzyme-B12 catalyzed diol dehydrase
reaction of 1,2-dihydroxyethane has been examined
theoretically Link to the ACS J.Phys.Chem B for
which you need a subscription.
1998: Methylcobalt, methylnickel, iron-carbonyl, and
acetylmetal intermediates are identifiable
1997:
We had an amazing Molecular Spring from Bernhard
Kräutler's group at Innsbruck.