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Publication List
2023
2022
2021
2020
2019
2018
2017
2016
2015
2014
2013
2012
2011
2010
2009
2008
2007
2006
2005
Pre-2005
2023
398. Stereospecific Conversion of Boronic Esters into Enones using Methoxyallene: Application in the Total Synthesis of 10-Deoxymethynolide
397. Convergent Deboronative and Decarboxylative Phosphonylation Enabled by the Phosphite Radical Trap “BecaP”
396. Photoredox-Catalyzed Decarboxylative Bromination, Chlorination and Thiocyanation Using Inorganic Salts
395. Iridium-Catalyzed Asymmetric Difunctionalization of C–C σ-Bonds Enabled by Ring-Strained Boronate Complexes
394. Copper-Mediated Dehydrogenative C(sp3)–H Borylation of Alkanes
393. De Novo Synthesis of Dihydrobenzofurans and Indolines and Its Application to a Modular, Asymmetric Synthesis of Beraprost
392. Application of Enantioselective Sulfur Ylide Epoxidation to a Short Asymmetric Synthesis of Bedaquiline, a Potent Anti-Tuberculosis Drug
391. Conformationally Controlled sp3-Hydrocarbon-Based α-Helix Mimetics
390. Synthesis and Applications of Bicyclo[1.1.0]butyl and Azabicyclo[1.1.0]butyl Organometallics
389. Synthesis of Dihydropyridine Spirocycles by Semi-Pinacol-Driven Dearomatization of Pyridines
2022
388. Application of Lithiation–Borylation to the Total Synthesis of (−)-Rakicidin F
387. Strain-Release Driven Epoxidation and Aziridination of Bicyclo[1.1.0]butanes via Palladium Catalyzed σ-Bond Nucleopalladation
386. Iterative synthesis of 1,3-polyboronic esters with high stereocontrol and application to the synthesis of bahamaolide A
385. Automated Stereocontrolled Assembly-Line Synthesis of Organic Molecules
384. Four-Component Strain-Release-Driven Synthesis of Functionalized Azetidines
383. Dual-Gradient Unified Chromatography: A New Paradigm for Versatility in Simultaneous Multicomponent Analysis
382. Facile Conversion of α-Amino Acids to α-Amino Phosphonates by Decarboxylative Phosphorylation using Visible-Light Photocatalysis
381. Dual Nickel/Photoredox-Catalyzed Site-Selective Cross-Coupling of 1,2-Bis-Boronic Esters Enabled by 1,2-Boron Shifts
380. Organocatalytic Dimerization of Succinaldehyde
379. Diastereodivergent Synthesis of Cyclopentyl Boronic Esters Bearing Contiguous Fully Substituted Stereocenters
378. Stereocontrolled Total Synthesis of Bastimolide B Using Iterative Homologation of Boronic Esters
377. Selective Coupling of 1,2-Bis-Boronic Esters at the more Substituted Site through Visibile-Light Activation of Electron Donor-Acceptor Complexes
376. Trapping-Enrichment Multi-dimensional Liquid Chromatography with On-Line Deuterated Solvent Exchange for Streamlined Structure Elucidation at the Microgram Scale
375. Lithiation-Borylation Methodology in the Total Synthesis of Natural Products
2021
374. Sequential Photocatalytic Reactions for the Diastereoselective Synthesis of Cyclobutane Scaffolds
373. Strain-Release-Driven Friedel-Crafts Spirocyclization of Azabicyclo[1.1.0]butanes
372. Direct Observation of Reactive Intermediates by Time-Resolved Spectroscopy Unravels the Mechanism of a Radical-Induced 1,2-Metalate Rearrangement
371. Conformationally Controlled Linear and Helical Hydrocarbons Bearing Extended Side Chains
370. Chiral Benzothiophene Synthesis via Enantiospecific Coupling of Benzothiophene S-Oxides with Boronic Esters
369. Synthesis of Dysoxylactam A Using Iterative Homologation of Boronic Esters
368. Highly Diastereoselective Strain-Increase Allylborations: Rapid Access to Alkylidenecyclopropanes and Alkylidenecyclobutanes
367. Diastereoselective Photoredox-Catalyzed [3 + 2] Cycloadditions of N-Sulfonyl Cyclopropylamines with Electron-Deficient Olefins
366. Strain-Release Driven Spirocyclization of Azabicyclo[1.1.0]butyl Ketones
365. The Matteson Reaction
364. Studies on the lithiation, borylation, and 1,2-metalate rearrangement of O-cycloalkyl 2,4,6-triisopropylbenzoates
363. Divergent, Strain-Release Reactions of Azabicyclo[1.1.0]butyl Carbinols: Semipinacol or Spiroepoxy Azetidine Formation
362. Origin of stereocontrol in the Matteson reaction: Importance of attractive electrostatic interactions
2020
361. Metal-free photoinduced C(sp3)–H borylation of alkanes
360. α-Selective Ring Opening Reactions of Bicyclo[1.1.0]butyl Boronic Ester with Nucleophiles
359. Stuart Warren (24 Dec 1938–22 Mar 2020)
358. Photoinduced Fragmentation Borylation of Cyclic Alcohols and Hemiacetals
357. Enantioselective Total Synthesis of (–)-Finerenone using Asymmetric Transfer Hydrogenation
356. Difunctionalization of C–C σ Bonds Enabled by the Reaction of Bicyclo[1.1.0]butyl Boronate Complexes with Electrophiles: Reaction Development, Scope, and Stereochemical Origins
355. How big is the pinacol boronic ester as a substituent?
354. Total Synthesis of Thromboxane B2 via a Key Bicyclic Enal Intermediate
353. Prostaglandin Total Synthesis Enabled by the Organocatalytic Dimerization of Succinaldehyde
352. Iridium-Catalyzed Enantioselective Synthesis of Chiral Bicyclo[1.1.1]pentanes by 1,3-Difunctionalization of [1.1.1]Propellane
351. Stereospecific 1,2-Migrations of Boronate Complexes Induced by Electrophiles
350. Synthesis, Stability, and Biological Studies of Fluorinated Analogues of Thromboxane A2
349. Ring-Expansion Induced 1,2-Metalate Rearrangements: Highly Diastereoselective Synthesis of Cyclobutyl Boronic Esters
348. Odd–even alternations in helical propensity of a homologous series of hydrocarbons
347. Divergent, stereospecific mono- and difluoromethylation of boronic esters
346. Visible Light-Driven Strain-Increase Ring Contraction Allows the Synthesis of Cyclobutyl Boronic Esters
345. 1,3-Difunctionalizations of [1.1.1]Propellane via 1,2-Metallate Rearrangements of Boronate Complexes
344. Decarboxylative Conjunctive Cross-coupling of Vinyl Boronic Esters using Metallaphotoredox Catalysis
343. Ring-Opening Lithiation–Borylation of 2-Trifluoromethyl Oxirane: A Route to Versatile Tertiary Trifluoromethyl Boronic Esters
2019
342. Total synthesis of (−)-α-cyclopiazonic acid: a study in perseverance
341. Methylenespiro[2.3]hexanes via Nickel-Catalyzed Cyclopropanations with [1.1.1]Propellane
340. Boron “Ate” Complexes for Asymmetric Synthesis
339. Triphenylphosphine and sodium iodide: a new catalyst combination to rival precious metal complexes in visible light photoredox catalysis
338. Photoinduced Deoxygenative Borylations of Aliphatic Alcohols
337. 1,2-Boron Shifts of β-Boryl Radicals Generated from Bis-boronic Esters Using Photoredox Catalysis
336. Vinylidene Homologation of Boronic Esters and its Application to the Synthesis of the Proposed Structure of Machillene
335. Radical Addition to Strained σ-Bonds Enables the Stereocontrolled Synthesis of Cyclobutyl Boronic Esters
334. Strain Release of Donor–Acceptor Cyclopropyl Boronate Complexes
333. Strain-Release-Driven Homologation of Boronic Esters: Application to the Modular Synthesis of Azetidines
332. Catalyst-Free Deaminative Functionalizations of Primary Amines via Photoinduced Single-Electron Transfer
331. Photoredox‐Catalyzed Cyclobutane Synthesis via a Deboronative Radical Addition–Polar Cyclization Cascade
330. Carbopalladation of C–C σ-bonds enabled by strained boronate complexes
329. Enantiospecific Synthesis of ortho‐Substituted 1,1‐Diarylalkanes by a 1,2‐Metalate Rearrangement/anti‐SN2' Elimination/Rearomatizing Allylic Suzuki‐Miyaura Reaction Sequence
328. Complex Boron-Containing Molecules through a 1,2-Metalate Rearrangement/anti-SN2′ Elimination/Cycloaddition Reaction Sequence
2018
327. Investigation of the Deprotonative Generation and Borylation of Diamine-Ligated α-Lithiated Carbamates and Benzoates by in situ IR spectroscopy
326. Chiral Aniline Synthesis via Stereospecific C(sp3)–C(sp2) Coupling of Boronic Esters with Aryl Hydrazines
325. Synthesis of Functionalized Cyclopropanes from Carboxylic Acids via a Radical Addition‐Polar Cyclization Cascade
324. Photoinduced Deaminative Borylation of Alkylamines
323. (–)-Cytisine: Access to a stereochemically defined and functionally flexible piperidine scaffold
322. Synthesis of Isothiocineole and Application in Multigram-Scale Sulfur Ylide Mediated Asymmetric Epoxidation and Aziridination
321. Re‐optimization of the Organocatalyzed Double Aldol Domino Process to a Key Enal Intermediate and its Application to the Total Synthesis of Δ¹²‐Prostaglandin J₃
320. Enantiodivergent Synthesis of Allenes by Point to Axial Chirality Transfer
319. Stereo- and Regiocontrolled Methylboration of Terminal Alkynes
318. (S)‐1‐(Trimethylstannyl)ethyl 2,4,6‐Triisopropylbenzoate and (R)‐1‐(Trimethylstannyl)ethyl 2,4,6‐Triisopropylbenzoate [Review]
317. Enantiospecific Three-Component Alkylation of Furan and Indole
316. CD1b Tetramers Identify T Cells that Recognize Natural and Synthetic Diacylated Sulfoglycolipids from Mycobacterium tuberculosis
315. Visible-Light-Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to γ-Amino Boronic Esters
314. Enantioselective Synthesis of the Cyclopiazonic Acid Family Using Sulfur Ylides
313. ortho-Directing Chromium Arene Complexes as Efficient Mediators for Enantiospecific sp2–sp3 Cross-Coupling Reactions
312. Gilbert Stork (1921–2017)
311. Stereocontrolled synthesis of polypropionate fragments based on a building block assembly strategy using lithiation-borylation methodologies
2017
310. Pinacolborane: Second Update [Review]
309. Enantiospecific sp2–sp3 Coupling of o- and p-Phenols with Secondary and Tertiary Boronic Esters
308. Synthesis of Alfaprostol and PGF2α through 1,4-Addition of an Alkyne to an Enal Intermediate as the Key Step
307. Homologation of Boronic Esters with Lithiated Epoxides
306. Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles
305. Asymmetric Synthesis of Secondary and Tertiary Boronic Esters [Review]
304. α-Sulfinyl Benzoates as Precursors to Li and Mg Carbenoids for the Stereoselective Iterative Homologation of Boronic Esters
303. Asymmetric Synthesis of Tertiary Alcohols and Thiols via Non-Stabilized Tertiary α-Oxy- and α-Thio-Organolithiums
302. Synergy of synthesis, computation and NMR reveals correct baulamycin structures
301. 50 Years of Zweifel Olefination: A Transition-Metal-Free Coupling [Review]
300. Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes
299. Enantiospecific Synthesis of ortho-Substituted Benzylic Boronic Esters by a 1,2-Metalate Rearrangement/1,3-Borotropic Shift Sequence
298. Alkynyl Moiety for Triggering 1,2-Metallate Shifts: Enantiospecific sp2-sp3 Coupling of Boronic Esters with p-Arylacetylenes
297. Photoinduced decarboxylative borylation of carboxylic acids
296. Synthesis of Functionalized Alkenes by a Transition-Metal-Free Zweifel Coupling
295. Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling
294. Merging Photoredox with 1,2-Metallate Rearrangements: The Photochemical Alkylation of Vinyl Boronate Complexes
293. Iterative assembly line synthesis of polypropionates with full stereocontrol
292. Stereospecific functionalizations and transformations of secondary and tertiary boronic esters [Review]
291. Selective uni- and bidirectional homologation of diborylmethane
290. Enantiospecific Trifluoromethyl-Radical-Induced Three-Component Coupling of Boronic Esters with Furans
289. Stereocontrolled Total Synthesis of (−)-Stemaphylline
288. Stereodivergent Olefination of Enantioenriched Boronic Esters
2016
287. (2-Bromoethyl)diphenylsulfonium Trifluoromethanesulfonate
286. Short Enantioselective Total Synthesis of Tatanan A and 3-epi-Tatanan A Using Assembly-Line Synthesis
285. Regio- and Stereoselective Homologation of 1,2-Bis(Boronic Esters): Stereocontrolled Synthesis of 1,3-Diols and Sch 725674
284. Development of Enantiospecific Coupling of Secondary and Tertiary Boronic Esters with Aromatic Compounds
283. Synthesis of 3-Aryl-1-aminopropane Derivatives: Lithiation–Borylation–Ring-Opening of Azetidinium Ions
282. Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions
281. Enantiospecific Alkynylation of Alkylboronic Esters
280. Tandem Allylboration–Prins Reaction for the Rapid Construction of Substituted Tetrahydropyrans: Application to the Total Synthesis of (−)-Clavosolide A
279. Activation of the SN2 Reaction by Adjacent π Systems: The Critical Role of Electrostatic Interactions and of Dissociative Character
2015
278. Reagent-Controlled Lithiation–Borylation
277. Synthesis of 6- and 7-Membered N-Heterocycles Using α-Phenylvinylsulfonium Salts
276. Synthesis of Enantioenriched Alkylfluorides by the Fluorination of Boronate Complexes
275. Short Convergent Synthesis of the Mycolactone Core Through Lithiation–Borylation Homologations
274. Stereospecific Coupling of Boronic Esters with N-Heteroaromatic Compounds
273.Structure and Reactivity of Boron-Ate Complexes Derived from Primary and Secondary Boronic Esters
272.Enantioselective installation of adjacent tertiary benzylic stereocentres using lithiation–borylation–protodeboronation methodology. Application to the synthesis of bifluranol and fluorohexestrol
271.Palladium-Catalyzed Reactions of Allylic Boronic Esters with Nucleophiles: Novel Umpolung Reactivity
270. Synthesis of Prostaglandin Analogues, Latanoprost and Bimatoprost, Using Organocatalysis via a Key Bicyclic Enal Intermediate
269.Toward Ideality: The Synthesis of (+)-Kalkitoxin and (+)-Hydroxyphthioceranic Acid by Assembly-Line Synthesis
2014
268. Lithium–Boron Chemistry: A Synergistic Strategy in Modern Synthesis
267. Stereospecific Couplings of Secondary and Tertiary Boronic Esters
266. Lithiation–Borylation Methodology and its Application in Synthesis
265. Oxidation of Carbon–Boron Bonds
264. Total Syntheses of Solandelactones E and F
263. Homologation of Boronic Esters with Organolithium Compounds: A Computational Assessment of Mechanism
262.Construction of Multiple, Contiguous Quaternary Stereocenters in Acyclic Molecules by Lithiation-Borylation
261.Synthesis of α-Substituted Vinylsulfonium Salts and Their Application as Annulation Reagents in the Formation of Epoxide- and Cyclopropane-Fused Heterocycles
260. Assembly-line synthesis of organic molecules with tailored shapes
259.
Highly Diastereoselective and Enantiospecific Allylation of Ketones and
Imines using Borinic Esters: Contiguous Quaternary Stereogenic Centers
258. Stereocontrolled Synthesis of 1,5-Stereogenic Centers through Three-Carbon Homologation of Boronic Esters.
257. Synthesis of hydroxyphthioceranic acid using a traceless lithiation-borylation-protodeboronation strategy.
256. Enantiospecific sp 2–sp 3 coupling of secondary and tertiary boronic esters.
255. Highly Selective Allylborations of Aldehydes Using α,α-Disubstituted Allylic Pinacol Boronic Esters.
254.
Stereocontrolled Synthesis of Adjacent Acyclic Quaternary-Tertiary
Motifs and its Application to a Concise Total Synthesis of
(−)-Filiformin.
253. Short Stereoselective Synthesis of the Phytophthora Universal Mating Hormone α1 Using Lithiation/Borylation Reactions.
252. Stereospecific conversion of alcohols into pinacol boronic esters using lithiation–borylation methodology with pinacolborane.
251. Asymmetric Addition of Chiral Boron-Ate Complexes to Cyclic Imminium Ions
2013
250. Synthesis of Enantioenriched Tertiary Boronic Esters by the Lithiation/Borylation of Secondary Alkyl Benzoates
249. Enantiospecific, Regioselective Cross-Coupling Reactions of Secondary Allylic Boronic Esters
248. Concise Synthesis of (+)-allo-Kainic Acid via MgI2-Mediated Tandem Aziridine Ring Opening–Formal [3 + 2] Cycloaddition
247. Practical and Highly Selective Sulfur Ylide-Mediated Asymmetric Epoxidations and Aziridinations Using a Cheap and Readily Available Chiral Sulfide: Extensive Studies To Map Out Scope, Limitations, and Rationalization of Diastereo- and Enantioselectivities
246. Efficient Synthesis of Cyclopropane-Fused Heterocycles with Bromoethylsulfonium Salt
245. Highly Diastereo-and Enantioselective Allylboration of Aldehydes using α-Substituted Allyl/Crotyl Pinacol Boronic Esters via in situ Generated Borinic Esters
244. Stereoselective Total Synthesis of (+)-Giganin and Its C10 Epimer by Using Late-Stage Lithiation–Borylation Methodology
243. Asymmetric Synthesis of 1-Heteroaryl-1-arylalkyl Tertiary Alcohols and 1-Pyridyl-1-arylethanes by Lithiation–Borylation Methodology
242. One-pot synthesis of 2,3,4,5,6-pentasubstituted tetrahydropyrans using lithiation-borylation, allylation and Prins cyclisation reactions.
2012
241. Bicyclo[2.2.1]heptan-2-one, 7,7-Dimethyl-1-(1S,3S,4R)-2-thiabicyclo[2.2.1]hept-3-yl-, (1S,4R)
240. Sulfonium, Ethenyldiphenyl-, 1,1,1-Trifluoromethanesulfonate
239. Diastereoselective Synthesis of CF3‐Substituted, Epoxide-Fused Heterocycles with β‐(Trifluoromethyl)vinylsulfonium Salts
238. Diastereo-divergent Synthesis of Trisubstituted Alkenes through Protodeboronation of Allylic Boronic Esters: Application to the Synthesis of the Californian Red Scale Beetle Pheromone.
237. Enantioselective Synthesis and Cross-coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates.
236. Bromoethylsulfonium triflates in stereoselective annulation reactions for the formation of fused bicyclic epoxides and aziridines.
235. Enantioselective Synthesis of (R)-Tolterodine using Lithiation/Borylation Protodeboronation Methodology.
234. Stereocontrolled organocatalytic synthesis of prostaglandin PGF2α in seven steps
233. The total synthesis of (–)-aplysin via a lithiation-borylation-propenylation sequence.
232. Application of the Lithiation-Borylation Reaction to the Rapid and Enantioselective Synthesis of the Bisabolane Family of Sesquiterpenes.
231. Synthesis of Enantioenriched Tertiary Boronic Esters from Secondary Allylic Carbamates. Application to the Synthesis of C30 Botryococcene.
230. An Efficient Synthesis of Azetidines with (2-Bromoethyl)sulfonium Triflate.
229. Stereocontrolled asymmetric synthesis of syn-E-1,4-diol-2-enes using allyl boronates and its application in the total synthesis of solandelactone F.
228. Synthesis of N-Vinyloxazolidinones and Morpholines from Aminoalcohols and Vinylsulfonium salts: Analysis of the Outcome’s Dependence on N-Protecting group by Nanospray Mass Spectrometry.
2011
227. Highly Enantioselective Synthesis of Tertiary Boronic Esters and their Stereospecific Conversion to other Functional Groups and Quaternary Stereocentres
226. Asymmetric Homologation of Boronic Esters with Lithiated Carbamates, Epoxides, and Aziridines
225. Enantioenriched Synthesis of Escitalopram using Lithiation-Borylation Methodology.
224. Enantioselective Syntheses of (+)-Sertraline and (+) Indatraline using Lithiation/Borylation Protodeboronation Methodology.
223. Ate Complexes of Secondary Boronic Esters as Chiral Organometallic-Type Nucleophiles for Asymmetric Synthesis.
This paper was highlighted in synfacts. pdf
222. Total Synthesis of (+)-Erogorgiaene Using Lithiation–Borylation Methodology, and Stereoselective Synthesis of Each of Its Diastereoisomers.
221. Use of Alkyl 2,4,6-Triisopropylbenzoates in the Asymmetric Homologation of Challenging Boronic Esters.
220. Palladium-Catalyzed Insertion of CO2 into Vinylaziridines: New Route to 5-Vinyloxazolidinones.
219. An Efficient Synthesis of Imidazolinium Salts using Vinyl Sulfonium Salts.
218. Sulfinamides as Highly Effective Amine Protecting Groups and their use in the Conversion of Aminoalcohols into Morpholines.
216. Palladium-Mediated Annulation of Vinyl Aziridines with Michael Acceptors. Stereocontrolled Synthesis of Substituted Pyrrolidines and Application to a Formal Synthesis of (–)-α-Kainic Acid.
215. Remote Chiral Induction in Vinyl Sulfonium Salt-Mediated Ring Expansion of Hemiaminals into Epoxide-Fused Azepines
214. Enantioselective Construction of Quaternary Stereogenic Centers from Tertiary Boronic Esters: Methodology and Applications.
213. Asymmetric Synthesis of Tertiary and Quaternary Allyl- and Crotylsilanes via the Borylation of Lithiated Carbamates.
This paper was highlighted in synfacts. (pdf)
212. Synthesis of Highly Enantioenriched C-Tertiary Amines From Boronic Esters: Application to the Synthesis of Igmesine.
2010
211. Epoxidation and Aziridination of Carbonyl Groups and Imines
210. Protodeboronation of Tertiary Boronic Esters: Asymmetric Synthesis of Tertiary Alkyl Stereogenic Centers.
This paper was highlighted at the Organic Synthesis Portal.
209. Ring-opening of NH-Aziridines with Thiols in Ionic Liquids - Application to the Synthesis of Aminosulfide Catalysts for Asymmetric Epoxidation of Aldehydes.
208. Asymmetric Total Synthesis of Solandelactone E: Stereocontrolled Synthesis of the 1,4-diol-2-ene core via Lithiation-Borylation-Allylation Sequence
207. Benzylic Boron Reagents Behaving as Allylic Boron Reagents towards Aldehydes: A New Asymmetric Reaction Leading to Homoallylic Alcohols with Concomitant Dearomatisation
206. Synthesis of Quinine and Quinidine using Sulfur Ylide-mediated Asymmetric Epoxidation as a Key Step.
205. Synthesis of Highly Functionalized 2,5-Disubstituted Pyrrolidines via an Aza-Morita-Baylis-Hillman-type Reaction.
204. Full Chirality Transfer in the Conversion of Secondary Alcohols into Tertiary Boronic Esters and Alcohols Using Lithiation-Borylation Reactions
203. On the Mechanism of Ylide-Mediated Cyclopropanations: Evidence for a Proton Transfer Step and its Effect on Stereoselectivity.
202. Asymmetric Synthesis of Allylsilanes by the Borylation of Lithiated Carbamates: Formal Total Synthesis of (-)-Decarestrictine D.
Angew. Chem. Int. Ed., 2010, 49, 4264-4268. doi | pdf
Highlighted in Chemistry World: Totally Synthetic
Highlighted in Chemistry World: Totally Synthetic
201. A Novel Asymmetric Azaspirocyclisation using a Morita Baylis Hillman-type Reaction.
200. Application of the Lithiation-Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry.
199. Practical and Highly Selective Sulfur Ylide-Mediated Asymmetric Epoxidations and Aziridinations Using a Cheap and Readily Available Chiral Sulfide. Application to the Total Synthesis of Quinine and Quinidine.
J. Am. Chem. Soc., 2010, 132, 1828-1830. doi | pdf
Presented in Chemistry By Design
Highlighted in Chemistry World
Presented in Chemistry By Design
Highlighted in Chemistry World
198. Stereoeselective Synthesis of trans-β-Lactams by Palladium-Catalysed Carbonylation of Vinyl Aziridnes. (pdf, 1.0Mb)
Chem. Commun., 2010, 46, 267-269.
2009
197. Homologation and Alkylation of Boronic Esters and Boranes by 1,2-Metallate Rearrangement of Boron Ate Complexes
196. Improved Method for the Conversion of Pinacolboronic Esters into Trifluoroborate Salts. Facile Synthesis of Chiral Secondary and Tertiary Trifluoroborates. (pdf)
Tetrahedron, 2009, 65, 9956-9960.
195. New Uses for Old Building Blocks
194. Stereocontrolled Synthesis of Carbon Chains Bearing Contiguous Methyl Groups by Iterative Boronic Ester Homologations. Application to the Total Synthesis of (+)-Faranal. (pdf)
Angew. Chem. Int. Ed., 2009, 48, 6317-6319.
193. Complete Stereoretention in the Rhodium-Catalyzed 1,2-Addition of Chiral Secondary and Tertiary Alkyl Potassium Trifluoroborate Salts to Aldehydes. (pdf)
Angew. Chem. Int. Ed., 2009, 48, 6289-6292.
192. The Fate of the tert-Butylsulfinyl Auxiliary After Acid-Promoted Cleavage - a Method for Recycling t-BuSONH2. (pdf)
191. Asymmetric Hydroboration of 1,1-Disubstituted Alkenes. (pdf, 1.0Mb)
Angew. Chem. Int. Ed., 2009, 48, 1896-1898.
190. Stereocontrolled Synthesis of β-Amino Alcohols from Lithiated Aziridines and Boronic Esters. (pdf)
Angew. Chem. Int. Ed., 2009, 48, 1149-1152.
189. Bromoethylsulfonium salt - a More Effective Annulation Agent for the Synthesis of 6- and 7-Membered 1,4-Diheterocyclic Compounds. (pdf)
Org. Lett., 2009, 11, 257-260.
188. Homologation of Boronic Esters with Lithiated Epoxides for the Stereocontrolled Synthesis of 1,2 and 1,3-Diols, and 1,2,4-Triols. (pdf)
Org. Lett. 2009, 11, 165-168.
2008
187. Synthesis of Epoxides by Carbonyl Epoxidation
186. Highly Enantioselective Conversion of Secondary Alcohols into Tertiary Alcohols with Broad Scope. (pdf, 3.3Mb)
Nature, 2008, 456, 778-782.
185. Synthesis and Application of Easily Recyclable Thiomorpholines for use in Sulfur Ylide-mediated Asymmetric Epoxidation of Aldehydes.
184. Sulfur Ylide Mediated Three-Component Aziridination and Epoxidation Reactions Using Vinyl Sulfonium Salts Thre-Component Aziridination and Epoxidation Reaction. (pdf)
Synlett, 2008, 2191-2195.
183. Direct Synthesis of Functionalized Allylic Boronic Esters From Allylic Alcohols and Inexpensive Reagents and Catalysts. (pdf)
Synthesis, 2008, 2293-2297.
182. Novel Annulation Reaction for the Synthesis of Morpholines, Thiomorpholines and Piperazines from β-Heteroatom Amino Compounds and Vinyl Sulfonium Salts. (pdf)
Angew. Chem. Int. Ed., 2008, 47, 3784-3786.
181. Epoxy-Annulations by Reactions of α-Amino Ketones with Vinyl Sulfonium Salts. Reagent Versus Substrate Control and Kinetic Resolution. (pdf)
Org. Lett., 2008, 10, 1501-1504.
180. Reactions of Silyl-Stabilised Sulfur Ylides with Organoboranes: Enantioselectivity, Mechanism, and Understanding. (pdf, 3.4Mb)
Org. Biomol. Chem., 2008, 6, 1185-1189.
179. Asymmetric Lithiation-Substitution of Amines Involving Rearrangement of Borates. (pdf)
Org. Lett., 2008, 10, 141-143.
178. Application of Furyl-Stabilized Sulfur Ylides to a Concise Synthesis of 8a-epi-Swainsonine. (pdf)
Chem. Commun., 2008, 120-122.
2007
177. Chalcogenides as Organocatalysts
176. Ylide Based Reactions
175. Trimethylsulfoxonium Iodide [first update]
174. Mechanism of the Morita-Baylis-Hillman Reaction: A Computational Investigation.
173. Asymmetric Sulfur Ylide Reactions with Boranes: Scope and Limitations, Mechanism and Understanding.
J. Am. Chem. Soc., 2007, 129, 14632-14639.
172. A New Manifold for the Morita Reaction: Diene Synthesis from Simple Aldehydes and Acrylates/Acrylonitrile Mediated by Phosphines.
Chem. Commun., 2007, 4128-4130.
171. Lithiated Carbamates: Chiral Carbenoids for Iterative Homologation of Boranes and Boronic Esters.
170. Aminals as Substrates for Sulfur Ylides: A Synthesis of Functionalised Aziridines and N-Heterocycles.
Org. Lett., 2007, 9, 2099-2102.
169. New Reaction of Cyclic Aminal with Michael Acceptors Leading to β-Amido-α,β-unstaurated Carbonyl Compounds through a Morita-Baylis-Hillman Type Reaction. Enantiocontrol and Applications in Synthesis.
168. Asymmetric Synthesis of α-Substituted Allylic Boranes and their Application in Synthesis of iso-Agatharesinol.
167. Studies Towards a Biomimetic Synthesis of α-Cyclopiazonic Acid: Synthesis of 5-Substituted Isoxazole-4-carboxylic Esters.
Arkivoc, 2007, part V, 139-151.
2006
166. Rearrangements of Organozinc Compounds
165. Towards an Understanding of the Factors Responsible for the 1,2-Migration of Alkyl Groups in Borate Complexes
164. Catalityc Asymmetric Sulfur Ylide Mediated Epoxidation of Carbonyl Compounds
163. Asymmetric synthesis of epoxides and aziridines from aldehydes and imines
162. Dimethylsulfoxonium Methylide (1995)
161. Dimethylsulfonium Methylide (1995)
160. BF3·OEt2 and TMSOTf: A Synergistic Combination of Lewis Acids
Chem. Commun., 2006, 4434-4436.
159. The Use of Vinyl Sulfonium Salts in the Stereocontrolled Asymmetric Synthesis of Epoxide- and Aziridine-Fused Heterocycles: Application to the Synthesis of (-)Balanol
158. A Practical Synthesis of a [2,2,1] Bicyclic Chiral Sulfide for Asymmetric Transformations
157. Novel, Readily-Synthesised, Chiral Sulfides as Reagents for Asymmetric Epoxidation
156. Hemiaminals as Substrates for Sulfur Ylides: Direct Asymmetric Syntheses of Functionalised Pyrrolidines and Piperidines
Chem. Commun., 2006, 2156-2158.
155. Ligand Induced Control of C-H Versus C-C Insertion Reactions of Rh Carbenes
154. Reactivity and Selectivity in the Wittig Reaction: A Computational Study
153. Highly Enantioselective Synthesis of Glycidic Amides Using Camphor-Derived Sulfonium Salts. Mechanism and Applications in Synthesis
152. Is phenyl a Good Migrating Group in the Rearrangement of Organoborates Generated from Sulfur Ylides?
Chem. Commun., 2006, 741-743.
151. Delineation of the Factors Governing Reactivity and Selectivity in Epoxide Formation from Ammonium Ylides and Aldehydes
Org. Biomol. Chem., 2006, 4, 621-623.
150. Optimization of the Mizoroki-Heck Reaction using Design of Experiment (DoE)
149. Asymmetric Sulfonium Ylide Mediated Cyclopropanation: Stereocontrolled Synthesis of (+)-LY354740
2005
148. The Use of Tosylhydrazone Salts as a Safer Alternative to Handling Diazo Compounds and their Applications in Organic Synthesis
147. α-Substituted Sulfur Ylides
146. Reagent Controlled Addition of Chiral Sulfur Ylides to Chiral Aldehydes
145. On the Origin of High E Selectivity in the Wittig Reaction of Stabilized Ylides: Importance of Dipole-Dipole Interactions
144. Enantioselective α-Arylation of Cyclohexanones with Diaryl Iodonium Salts: Application to the Synthesis of (-)-Epibatidine
143. Highly regioselective and Diastereoselective Epoxidation of Allylic amines with Oxone
142. Highly Diastereoselective Diels-Alder Reactions of Baylis-Hillman Adducts
141. On the Importance of Leaving Group Ability in Reactions of Ammonium, Oxonium, Phosphonium and Sulfonium Ylides
140. Carboxylate-Stabilised Sulfur Ylides (Thetin Salts) in Asymmetric Epoxidation for the Synthesis of Glycidic Acids. Mechanism and Implications
139. Separation of Pyrrolidine Allylation Products by Diastereoselective Enzymatic Ester Hydrolysis
138. Synthesis and Applications of Chiral Organoboranes Generated from Sulfonium Ylides
137. Re-evaluation of the Mechanism of the Baylis-Hillman Reaction - Implications for Asymmetric Catalysis
136. Simple Preparation of Trans-epoxides via Ylide Intermediates
Pre-2005
135. Sulfur Ylides
134. Catalytic Asymmetric Sulfur Ylide-Mediated Synthesis of epoxidation of Carbonyl Compounds: Scope, Selectivity and Applications in Synthesis
133. Lithiation and Reactions of Stilbene oxides: Synthetic Utility
132. Application of Sulfur Ylide Mediated Epoxidations in the Asymmetric Synthesis of β-Hydroxy-δ-Lactones. Synthesis of a Mevinic Acid Analogue and (+)-Prelactone B
131. Asymmetric Synthesis of Avenaciolide via Cascade Palladium Catalysed Cyclisation-Carbonylation of Bromodienes
130. A Concise Asymmetric Route to the Bridged Bicyclic Tropane Alkaloid Ferruginine using Enyne Ring Closing Metathesis
129. Effect of Sulfide Structure on Enantioselectivity in Catalytic Asymmetric Epoxidation of Aldehydes; Mechanistic Insights and Implications
128. The Complexity of Catalysis: Origins of Enantio- and Diastereocontrol in Sulfur Ylide Mediated Epoxidation Reactions
127. Profile of V. K. Aggarwal
126. Catalytic Asymmetric Nazarov Reactions Promoted by Chiral Lewis Acid Complexes
125. Highly Diastereoselective Simmons-Smith Cyclopropanation of Allylic Amines
124. Diastereoselective Synthesis of Cyclopropane Amino Acids Using Diazo Compounds Generated In Situ
123. Asymmetric Sulfur Ylide Mediated Aziridination: Application in the Synthesis of the Side Chain of Taxol
122. Tandem Formation and [2,3] Rearrangement of Methylene Ammonium Ylides Derived from Amines and the Simmons-Smith Reagent
121. Palladium catalysed cyclisation-carbonylation of enynes to give cyclic γ,δ-unsaturated acids
120. Highly Diastereoselective 1,3-Dipolar Cycloaddition Reactions of trans-2-Methylene-1,3-dithiolane 1,3-dioxide with 3-Oxidopyiridinium and 3-Oxidopyrylium Betaines: a Route to the Tropane Skeleton
119. Sulfur Ylide Mediated Synthesis of Highly Functionalised and Trisubstituted Epoxides with High Enantioselectivity. Application to the Synthesis of CDP 840
118. A New Protocol for the in situ Generation of Aromatic, Heteroaromatic and Unsaturated Diazocompounds and its Application in Catalytic and Asymmetric Epoxidation of Carbonyl Compounds. Extensive Studies to map out Scope and Limitations and Rationalization of Diastereo- and Enantioselectivities
117. Highly Enantioselective Oxidations of Ketene Dithioacetals: Formation of Trans Bis-sulfoxides without Contamination from Meso Isomers
116. A Novel One-pot Method for the Preparation of Pyrazoles by 1,3-Dipolar Cycloadditions of Diazo Compounds Generated In Situ
115. Generation of Phosphoranes Derived from Phosphites. A New Class of Phosphorus Ylides Leading to High E Selectivity with Semi-Stabilizing Groups in Wittig Olefinations
114. New insights in the Mechanism of Amine Catalysed Epoxidation: Dual Role of Protonated Ammonium Salts as Both Phase Transfer Catalysts and Activators of Oxone
113. The use of Enantiomerically Pure Ketene Dithioacetal bis-Sulfoxides in Highly Diastereoselective Intramolecular Nitrone Cycloadditions. Application in the Total Synthesis of α-Amino Acids, (-)-Cispentacin and the First Asymmetric Synthesis of 4-Amino-pyrrolidine-3-carboxylic acid
112. Correlation Between pKa and Reactivity of Quinuclidine-based Catalysts in the Baylis-Hillman Reaction - Discovery of Quinuclidine as Optimum Catalyst Leading to Substantial Enhancement of Scope
111. Extension of Ring Closing Metathesis Methodology to the Synthesis of Carbocyclic Methyl and Silyl Enol Ethers
110. Ketene Claisen Rearrangement of Camphor-derived 1,3-oxathianes: complete control of tertiary and quaternary stereogenic centres
109. Application of the Chiral Acyl Anion Equivalent, trans-1,3-Dioxide, to an Asymmetric Synthesis of (R)-Salbutamol
108. A palladium catalysed cyclisation-carbonylation of bromodienes: control in carbonylation over facile beta-hydride elimination
107. Sulphur ylide-mediated stereoselective synthesis of a stable ferrocenyl epoxide
106. Unraveling the mechanism of epoxide formation from sulfur ylides and aldehydes
105. Synthesis of epoxides from aldehydes and tosylhydrazone salts catalysed by triphenylarsine: complete trans selectivity for all combinations of coupling partners
104. Unexpected side reactions of imidazolium-based ionic liquids in the base-catalysed Baylis-Hillman reaction
103. Highly enantioselective Darzens reaction of a camphor-derived sulfonium amide to give glycidic amides and their applications in synthesis
102. A new method for the preparation of silyl enol ethers from carbonyl compounds and (Trimethylsilyl)diazomethane in a regiospecific and highly stereoselective manner
101. Epoxidation of alkenes by amine catalyst precursors: Implication of aminium ion and radical cation intermediates (vol 122, pg 8317, 2000)
100. Synthesis of new, highly hindered C-2-symmetric trans (2S,5S)- disubstituted pyrrolidines
99. Highly diastereoselective aziridination of imines with trimethylsilyldiazomethane. Subsequent silyl substitution with electrophiles, ring opening, and metalation of C- silylaziridines - A cornucopia of highly selective transformations
98. Highly diastereoselective nitrone cycloaddition onto a chiral ketene equivalent: Asymmetric synthesis of cispentacin
97. The use of enantiomerically pure N-sulfinimines in asymmetric Baylis-Hillman reactions
96. Rate Acceleration of the Baylis-Hillman Reaction in Polar Solvents (Water and Formamide). Dominant Role of Hydrogen Bonding not Hydrophobic Effects are Implicated
95. Developments in the Simmons-Smith Mediated Epoxidation Reaction
94. Additions of stabilised and semi-stabilised sulfur ylides to tosyl protected imines: are they under kinetic or thermodynamic control?
93. Synthesis and evaluation of a broad range of chiral sulfides for asymmetric sulfur ylide epoxidation of aldehydes
92. Catalytic Cyclopropanation of Alkenes using Diazo Compounds Generated In Situ. A novel route to 2-Arylcyclopropylamines
91. A novel procedure for the synthesis of aziridines: application of Simmons-Smith reagents to aziridination
90. Scope and limitations in sulfur ylide mediated catalytic asymmetric aziridination of imines: use of phenyldiazomethane, diazoesters and diazoacetamides
89. Application of Chiral Sulfides to Catalytic Asymmetric Aziridination and Cyclopropanation with in situ Generation of the Diazocompound
88. Catalytic Asymmetric Synthesis of Epoxides from Aldehydes using Sulfur Ylides with in situ Generation of Diazocompounds
87. Profile of Professor Varinder K. Aggarwal (Corday Morgan Award)
86. A simple, user-friendly process for the homologation of aldehydes using tosylhydrazone salts
85. Highly Selective Aziridination of Imines Using Trimethylsilyldiazomethane and Applications of C-Silylaziridines in Synthesis
84. Amidine-promoted addition of chloroform to carbonyl compounds
83. Epoxidation of alkenes by amine catalyst precursors: Implication of aminium ion and radical cation intermediates
82. Catalytic cyclopropanation of electron deficient alkenes mediated by chiral and achiral sulfides: scope and limitations in reactions involving phenyldiazomethane and ethyl diazoacetate
81. Stereochemical control in the synthesis of tetrahydrofurans by cyclisation of diols with [1,2]-phenylsulfanyl migration
80. Copper(II)-bisoxazoline-catalysed asymmetric Diels-Alder reactions of alpha-thioacrylates
79. Epoxidation of Aldehydes and Enones
78. Sulfur Ylide Mediated Catalytic Asymmetric Epoxidation and Aziridination
77. The Development and Use of Ketene Equivalents in [4+2] Cycloadditions for Organic Synthesis
76. Diastereomerically pure spirocyclic bis-sulfinyl oxiranes and their application to the asymmetric synthesis of alpha-amino amides
75. A formal synthesis of (+)-pyripyropene A using a biomimetic epoxy- olefin cyclisation: effect of epoxy alcohol/ether on cyclisation efficiency
74. [2,3]-Sigmatropic Rearrangement of Allylic Sulfur Ylides Derived from Trimethylsilyldiazomethane (TMSD)
73. Enantioselective deprotonation of 4-tert-butylcyclohexanone by conformationally constrained chiral lithium amide bases
72. Superior amine catalysts for the Baylis-Hillman reaction: the use of DBU and its implications
71. An improved resolution of 2-methyl piperidine and its use in the synthesis of homochiral trans-2,6-dialkyl piperidines
70. A Formal Asymmetric Synthesis of (+)-Anatoxin-a Using an Enantioselective Deprotonation Strategy on an Eight Membered Ring
69. A formal synthesis of (+)-pyripyropene A using a biomimetic epoxy- olefin cyclisation
68. The effects of different ester and ketal protecting groups on the reactivity and selectivity of tartrate-derived silylketene acetals
67. Direct Asymmetric Epoxidation of Aldehydes using Catalytic Amounts of Enantiomerically Pure Sulfides
66. Sc(OTf)3, an efficient catalyst for addition of allyltrimethylsilane to aldehydes; Chemoselective addition to aldehydes in presence of ketones and in situ acylation (3 component coupling)
65. Studies on the asymmetric oxidation of ester derivatives of 1,3- dithiane-2-carboxylates. Asymmetric synthesis of trans-1,3-dithiane 1,3-dioxide
64. Metal- and ligand-accelerated catalysis of the Baylis-Hillman reaction
63. Highly diastereoselective epoxidation of ketene dithioacetal dioxides: A new approach to the asymmetric synthesis of alpha-amino amides
62. Catalytic Sylfur Ylide Reactions: Use of Diazoacetamides for the Diastereoselective Synthesis of Glycidic Amides
61. Catalytic asymmetric Diels-Alder reactions of alpha-thioacrylates for the preparation of norbornenone
60. (1R,3R)-2-methylene-1,3-dithiolane 1,3-dioxide: a highly reactive and highly selective chiral ketene equivalent in cycloaddition reactions with a broad range of dienes
59. Catalytic asymmetric epoxidation of aldehydes. Optimization, mechanism, and discovery of stereoelectronic control involving a combination of anomeric and Cieplak effects in sulfur ylide epoxidations with chiral 1,3-oxathianes
58. Sc(OTf)3, an efficient catalyst for formation and deprotection of geminal diacetates (acylals); Chemoselective protection of aldehydes in presence of ketones
57. Bifunctional catalysts for catalytic asymmetric sulfur ylide epoxidation of carbonyl compounds
56. 1,3-Dipolar cycloaddition reactions of trans-2-methylene-1,3- dithiolane 1,3-dioxide with nitrones
55. Camphor Derived 1,4-Oxathianes for Carbonyl Epoxidation
54. Catalytic Asymmetric Epoxidation and Aziridination Mediated by Sulfur Ylides. Evolution of a Project
Synlett, 1998, 329-336.
53. Scandium trifluoromethanesulfonate, an efficient catalyst for the intermolecular carbonyl-ene reaction and the intramolecular cyclisation of citronellal
52. Asymmetric Ylide Reactions: Epoxidation, Cyclopropanation, Aziridination, Olefination, and Rearrangement
51. A novel procedure for the synthesis of epoxides: Application of Simmons-Smith reagents toward epoxidation
50. Trans-1,3-Dithiane-1,3-Dioxide; a Chiral Acyl Anion Equivalent. Enantioselective Synthesis of ?-Hydroxy-Carboxylic Acids, Esters, Amides and Ketones
49. Catalytic Asymmetric Cyclopropanation of Electron Deficient Alkenes Mediated By Chiral Sulfides.
48. Dimethylsulfonium 9-Fluorenide - Solution Structure and Dynamic Behaviour of a Semi-Stabilised Sulfonium Ylide
47. Asymmetric total synthesis of (+)-carbocyclic uracil polyoxin C
46. Scope and Limitations in Palladium Catalysed Substitution Reactions of Unsaturated Fused Lactones
45. Trifluoromethanesulfonic Acid, an Efficient Catalyst for the Hetero Diels-Alder Reaction and an Improved Synthesis of Mefrasol
44. Addition of Benzyl Sulfonium Ylides to Aldehydes and Ketones. Are they under Kinetic or Thermodynamic Control?
43. Electronic Conference on Organometallic Chemistry: Catalytic Asymmetric Epoxidation
42. Seminars in Organic Synthesis: Asymmetric Epoxidation, XXII Summer School, Gargnano, Società Chimica Italiana
41. Catalytic and Asymmetric Aziridination Using Sulfur Ylides
40. Stereselective Epoxidation of bis-Sulfinyl Alkenes and Applications to the Asymmetric Synthesis of ?-Substituted Carboxylic Acids
39. Anion Reactions of Trans-1,3-Dithiolane-1,3-Dioxide with Aldehydes and Comparison with Trans-1,3-Dithiane-1,3-Dioxide
38. Direct Measurement of the Anomeric Effect in Sulfoxides: Conformational Analysis and X-Ray crystal Structures of 2-Halo-1,3-Dithiane-trans-1,3-Dioxide
37. 2-Halo-1,3-Dithiane-1,3-Dioxide : a Diastereoselective Carbonyl Anion Equivalent in Reactions with Aldehydes
36. First Examples of Metal and Ligand Accelerated Catalysis of the Baylis Hillman Reaction
35. Novel Catalytic and Asymmetric Process for Aziridination Mediated by Sulfur Ylides
34. Direct Asymmetric Epoxidation of Aldehydes Using Catalytic Amounts of Enantiomerically Pure Sulfides
33. First Synthesis and X-ray Crystal Structure of 1,2-(1,1'-Ferrocenediyl)ethene
32. A Novel Catalytic Cycle For The Synthesis Of Epoxides Using Sulfur Ylides
31. Scandium Trifluoromethanesulfonate, a Novel Catalyst for the Addition of Allyltrimethylsilane to Aldehydes
30. Palladium-Catalyzed Substitution Of Unsaturated Lactones - Application to the Synthesis Of Carbocyclic Polyoxins and Nikkomycins
29. Catalytic Asymmetric Synthesis of Epoxides Mediated by Chiral Iminium Salts
28. The Use Of Chiral Sulfides In Catalytic Asymmetric Epoxidation
27. (1R,3R)-2-Methylene-1,3-Dithiolane 1,3-Dioxide - a Highly Reactive and Highly Selective Chiral Ketene Equivalent
26. Anion reactions of 1,3-dithiane 1,3-dioxide with carbonyl-compounds - high diastereoselectivity with aromatic-aldehydes under conditions of equilibrium control
25. Complexes Containing a Lewis-Acid and Bronsted Acid For the Catalytic Asymmetric Diels-Alder Reaction
24. A Novel Catalytic Cycle For the Synthesis Of Epoxides Using Sulfur Ylides - Application to Base Sensitive Aldehydes
23. A novel catalytic cycle for the synthesis of epoxides using sulfur ylides, and application to the synthesis of cyclopropanes and aziridines V. K. Aggarwal; H. Abdel-Rahman; A. Thompson; B. Mattison; R. V. H. Jones Phosphorus Sulfur 1995, 283-292.
22. Synthesis of Sulfonium Salts by Sulfide Alkylation; an Alternative Approach
21. Asymmetric-Synthesis and Cycloaddition Chemistry Of Trans-2- Methylene-1,3-Dithiolane 1,3-Dioxide
20. Studies on the oxidation of 1,3-dithiane and 5,5-disubstituted analogues including X-ray crystal structure, equlibration studies and pKa measurements on selected oxides
19. Stereoselective Addition Reactions of Lithiated 2-Chloro-1,3-Dithiane-1,3-Dioxide to Aldehydes
18. Trans-1,3-dithiane-1,3-dioxide, a new chiral acyl anion equivalent for the preparation of masked activated acids - application to the synthesis of alpha-hydroxy acid-derivatives
17. Novel catalytic cycle for the synthesis of epoxides from aldehydes and sulfur ylides mediated by catalytic quantities of sulfides and Rh2(OAc)4
16. Asymmetric epoxidation using chiral sulfur ylides
15. The First Synthesis of the Novel 2,8-Dioxobicyclo[3,2,1]octane Ring System - a Key Feature of the Squalestatins
14. Enantioselective Transformations and Racemisation Studies of Heteroatom Substituted Organolithium Compounds
13. Chiral Ketene Equivalents for use in Asymmetric Synthesis
12. Chiral, Bisfunctionalisation of Substrates: a Powerful Strategy for the Asymmetric Synthesis of C2 Symmetric Compounds and its Application to the Synthesis of Enantiomerically Pure Trans-1,3-dithiane-1,3-dioxide 1
11. Trans-Dioxides of Cyclic Ketene Thioacetals: Highly Selective Chiral Ketene Equivalents
10. Highly Stereoselective Addition Reactions of Metallated Trans-1,3-dithiane-1,3-dioxide to Aldehydes
9. Synthesis, X-ray Crystal Structure, Equilibration Studies, and Anion Chemistry of Trans-1,3-dithiane-1,3-dioxide
8. Transformation of Cyclic a-Phenylthio Aldehydes by Stereoselective Aldol Reactions and Phenylthio Migration into Spirocyclic Lactones and Ethers, and E-Allylic Alcohols with 1,4-Related Chiral Centres
7. Trans-1,3-Dithiane-1,3-dioxide as a Potential Chiral Acyl Anion Equivalent
6. Additions of Aldehydes to Metallated Trans-1,3-dithiane-S,S-dioxide Under Conditions of Kinetic and Thermodynamic Control
5. Stereochemical Control in the Synthesis of Tetrahydrofurans by Cyclisation of Diols with Phenylthio Migration
4. A Review of S. G. Warren's Recent Work
3. Synthesis of Compounds with 1,4-Related Chiral Centres by Phenylthio Migration: Syn and Anti-E-2,4 Dimethylhex-3-ene-1,5-Diol
2. Allyl Sulphide Synthesis by Phenylthio Migration: Relationship between Stereochemistry of Starting Material and Regioselectivity of Double Bond Formation
1. Phenylthio (PhS) Migration in the Stereocontrolled Synthesis of Allylic Alcohols with 1,4-Related Chiral Centres